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3.1.1.d Monitoring the progression of phenolic maturity

Index of total polyphenols and anthocyanins

Phenolic ripeness pertains mainly to red grapes. A feature of grape ripening is the sudden accumulation of phenolic pigments which give the berry its technological value. Their production starts at the very beginning of a berry's development and stems from the catabolism of sugars. The main polyphenols are anthocyanins and tannins.

Anthocyanins are responsible for colour and accumulate until they reach a peak, their concentration then decreases as the grapes fully ripen.

Theoretical evolution of tannin and anthocyanin concentration

Anthocyanins are a good indicator of ripeness and it has been observed that a satisfactory level of ripeness is reached when a significant drop in anthocyanin levels is recorded. At this stage, the pigments have a lower concentration, but the breaking down of the cell walls encourages their diffusion in the liquid phase. Tannins also accumulate in the berry during ripening, their content in the seeds reaches a peak value before véraison. This content then decreases to become stable when the seeds are ripe. As for the tannins in the skins, they also mostly accumulate before véraison, and then more slowly until ripeness, eventually decreasing in concentration in the event of over-ripening.

Monitoring anthocyanins and tannins during ripening is therefore a key parameter in determining the harvest order. The optimal harvest date must take into account both the concentration of anthocyanins/tannins and their optimal extractability as well as the type of wine being produced. For a wine with ageing potential, a later harvest will allow better extractability of phenolic compounds. Conversely, for a lighter wine, the grapes can be harvested earlier to reduce extraction phenomena.

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